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But, as the history books tell us, anything can happen when these two collide.
Back at the 1990 World Cup, Brazil claimed Argentina had spiked their drinks after left-back Branco was left feeling drowsy out on the field, contributing to their 1-0 defeat.
Argentina are locked together on 24 points with Peru, who occupy the fourth automatic qualification spot, and trail their opponents this week only by virtue of fewer goals scored.
But Argentina must also keep an eye on the rear-view mirror, with Chile, the reigning Copa America champions, just a point behind them in sixth place.
Peru may not have qualified for the World Cup since 1982, but their current FIFA World Ranking of 12th is no accident.
Having lost four of their opening six qualifiers, Gareca's team have staged an astonishing revival to give themselves a great shot at reaching the finals and they head to Argentina having won their last three by a 2-1 scoreline.
Maradona apparently verified the story a few years back.